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The catalyst of MWC methanol cracking to produce hydrogen is a kind of copper as active component.A new catalyst composed of oxides of copper, zinc, aluminum, etc. It has high activity and good selectivity to methanol steam conversion to produce hydrogen and carbon dioxide.
The main characteristics of the catalyst
Manner Appearance color and shape: The catalyst is a black cylinder with a smooth, shiny surface.
2. Nominal size: Φ5 x 5 mm;Φ3.2 x 3.5 mm
Chemical composition (weight %) :
Group into | CuO | ZnO | Al2O3 |
Content % (weight) | 60 or higher | 5.0 or higher | 5.0 or higher |
4. Reactor density: 1.20 ~ 1.35 kg/liter
Mechanical crushing strength: ≥160 TON/cm
Catalytic activity
The measurements were made in a simulated reactor
The reactor: Φ25 x 1.5 mm
Catalyst size: Φ5 x 5 mm
Catalyst capacity: 60 ml
Reduction conditions:
Reduction pressure: Normal pressure
Reduction temperature: 110 ~ 230℃
Reduction airspeed: 500-1000h-1
Restore time: 50 hours
Reducing gas: containing H2 0.5 to 20% N 2Gas (or desulfurized gas)
Catalyst activity: space-time yield (converted gas) ≥ 600Nm3/ (m3, the cat, h).
2. Catalyst packaging and storage
The catalyst was packaged in a plastic bag and then put into an iron bucket.Indoor storage, strictly protect against damp, earthquake and toxic pollution. Do not roll on the ground during handling. Do not fall from more than 0.5 meters, or hit.
Under normal conditions, the catalyst can be stored for more than a year, the physical properties and activity of the catalyst will not be affected.
3. Catalyst heating, reduction and passivation
The MWC-612 catalyst is composed of oxides of copper, zinc and aluminum.Restore before use.
Restoring conditions:
Reduction pressure: Normal pressure
Reduction airspeed: 500-1000h-1
Reducing gas: containing H2 0.5 ~ 10% nitrogen (or desulfurized natural gas)
Reduction gas quality: O2 < 0.1%
H 2O < 0.2%
S < 0.1 PPM
Chloride < 0.1 PPM
Oil mist
3. The temperaturereduction procedure
The catalyst shall be reduced by heating before use. At different temperature segments, the heating rate was respectively 15 ° C /h, 10 ° C /h and 5 ° C /h. During the heating process, the hydrogen content in reducing gas was increased by stages (0.5 ~ 20%).
4. Get ready for driving
After reduction, stop adding hydrogen and reduce the reduction gas to 80% of the original flow.Prepare for normal start - up feeding. It is recommended that the feeding amount be 30 ~ 80% of normal operation.
5. Catalyst passivation
The catalyst must be passivated when it is discharged.
Passivation conditions:
Passivation gas: industrial pure nitrogen with an oxygen content of 0.1 ~ 5% (meter air).
Passivation airspeed: 300-1000h-1
Passivation pressure: normal pressure
After passivation, the catalyst can be removed.
Iv. Matters needing Attention
The reduction of the catalyst is a very important step, must be handled carefully.To ensure that the catalyst fully reduced, do not act in haste.
(2) After reduction, when preparing for normal feeding, to avoid the reactor temperature drop more than 10℃.
The MWC-612 catalyst can be operated at 260 ~ 280℃.The catalyst can maintain a low operating temperature in the early stage, and the operating temperature can be increased in the later stage to give full play to the maximum capacity of the catalyst, with the maximum temperature not exceeding 300℃.
(4) The disadvantage of copper catalyst is poor heat resistance, so whether the reduction of temperature or in the reaction operation to avoid the catalyst quench quenching heat. Otherwise, the change of copper grain will affect the activity and life of the catalyst.






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1. who are we?
We are based in Gansu, China, start from 2009,sell to Mid East(1.00%). There are total about 11-50 people in our office.
2. how can we guarantee quality?
Always a pre-production sample before mass production;
Always final Inspection before shipment;
3.what can you buy from us?
Pd catalyst,Pt catalyst,Ru catalyst,Pd-Pt catalyst,Methanol catalyst for hydrogen production
4. why should you buy from us not from other suppliers?
1\\Independent research and development 2\\product customization 3\\ technological innovation 4\\process design 5\\cooperate with Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences 6\\cooperate with advanced factories
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