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Sodium hydrosulfide is the chemical compound with the formula NaHS. This compound is the product of the half-neutralization of hydrogen sulfide (H2S) with sodium hydroxide. NaHS is a useful reagent for the synthesis of organic and inorganic sulfur compounds, sometimes as a solid reagent, more often as an aqueous solution. Solid NaHS is colorless, and typically smells like H2S owing to hydrolysis by atmospheric moisture. In contrast with sodium sulfide (Na2S), which is insoluble in organic solvents, NaHS, being a 1:1 electrolyte, is more soluble. Alternatively, in place of NaHS, H2S can be treated with an organic amine to generate an ammonium salt. Solutions of HS− are sensitive to oxygen, converting mainly to polysulfides, indicated by the appearance of yellow.
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Brownish solid yellow flakes. The Sodium Hydrosulphide will decomposed and release hydrogen disulfide at its melting point. It's dissolvable in water and ethanol, presenting strong alkaline when dissolved in water and generating hydrogen disulfide when reacting with acids.
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Thousands of tons of NaHS are produced annually. Its main uses are in cloth and paper manufacture as a makeup chemical for sulfur used in the kraft process, as a flotation agent in copper mining where it is used to activate oxide mineral species, and in the leather industry for the removal of hair from hides and tanning. Otherwise, it could also be used in wastewater treatment, paper pulping, chemical fertilizer industry, staining for sulfite in man-made fibers industry and so on.
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