13X HP Molecular Sieve Medical Oxygen Concentrator Zeolite Price

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Description


molecular sieves

 Molecular Sieves

Molecular sieves are crystalline metal aluminosilicates having a threedimensional interconnecting network of silica and alumina tetrahedra. Natural water of hydration is removed from this network by heating to produce uniform cavities which selectively adsorb molecules of a specific size.

A 4 to 8-mesh sieve is normally used in gasphase applications, while the 8 to 12-mesh type is common in liquidphase applications. The powder forms of the 3A, 4A, 5A and 13X sieves are suitable for specialized applications.

Long known for their drying capacity (even to 90°C), molecular sieves have recently demonstrated utility in synthetic organic procedures, frequently allowing isolation of desired products from condensation reactions that are governed by generally unfavorable equilibria. These synthetic zeolites have been shown to remove water, alcohols (including methanol and ethanol), and HCl from such systems as ketimine and enamine syntheses, ester condensations, and the conversion of unsaturated aldehydes to polyenals.

 

Table 1
Type3A
Composition0.6 K2O: 0.40 Na2O : 1 Al2O3 : 2.0 ± 0.1SiO2 : x H2O
DescriptionThe 3A form is made by substituting potassium cations for the inherent sodium ions of the 4A structure, reducing the effective pore size to ~3A, excluding diameter >3A, e.g., ethane.
Major ApplicationsCommercial dehydration of unsaturated hydrocarbon streams, including cracked gas, propylene, butadiene, acetylene; drying polar liquids such as methanol and ethanol. Adsorption of molecules such as NH3 and H2O from a N2/H2 flow. Considered a general-purpose drying agent in polar and nonpolar media.
 
Type4A
Composition1 Na2O: 1 Al2O3: 2.0 ± 0.1 SiO2 : x H2O
DescriptionThis sodium form represents the type A family of molecular sieves. Effective pore opening is 4A, thus excluding molecules of effective diameter >4A, e.g., propane.
Major ApplicationsPreferred for static dehydration in closed liquid or gas systems, e.g., in packaging of drugs, electric components and perishable chemicals; water scavenging in printing and plastics systems and drying saturated hydrocarbon streams.Adsorbed species include SO2, CO2, H2S, C2H4, C2H6, and C3H6. Generally considered a universal drying agent in polar and nonpolar media.
 
Type5A
Composition0.80 CaO : 0.20 Na2O : 1 Al2O3: 2.0 ± 0.1 SiO2: x H2O
DescriptionDivalent calcium ions in place of sodium cations give apertures of ~5A which exclude molecules of effective diameter >5A, e.g., all 4-carbon rings, and iso-compounds.
Major ApplicationsSeparation of normal paraffins frombranched-chain and cyclic hydrocarbons; removal of H2S, CO2 and mercaptans from natural gas. Molecules adsorbed include nC4H10, nC4H9OH, C3H8 to C22H46, and dichlorodifluoro-methane.
 
Type13X
Composition1 Na2O: 1 Al2O3 : 2.8 ± 0.2 SiO2 : xH2O
DescriptionThe sodium form represents the basicstructure of the type X family, with an effective pore opening in the 910¼ range. Will not adsorb(C4F9)3N, for example.
Major ApplicationsCommercial gas drying, air plantfeed purification (simultaneous H2O and CO2 removal) and liquid hydrocarbon/natural gas sweetening (H2S and mercaptan removal).

 

3A Molecular Sieve, is an alkali metal alumina silicate. It is the potassium form of the type A crystal structure.It has an effective pore opening of about 3 angstroms(0.3nm)This is large enough to allow in moisture, but excludes molecules such as unsaturated hydrocarbons which can potentially form polymers.

 

Properties and Characteristics of Molecular Sieve of 3A
TypeFormBead or Particle size

Diameter

(mm)

Bulk density

(g/ml)

Moisture

(%)

H2O capacity

(%)

Size ratio up to grade

(%)

Wear ratio

(%)

3Abead4-8 mesh3.0-5.0≥0.70≤1.5≥21.0≥98.0≤0.25
bead8-12mesh1.7-2.5≥0.70
pallet1/16(inch)1.6≥0.68≥96.0
pallet1/8(inch)3.2≤0.68
 
4A Molecular Sieve, is an alkali alumina silicate. It is the sodium form of the type A crystal structureIt has an effective pore opening of about 4 angstroms(0.4nm)It will adsorb most molecules with a kinetic diameter of less than 4 angstroms and exclude those larger.
 
Properties and Characteristics of Molecular Sieve of 4A
TypeFormBead or Particle size

Diameter

(mm)

Bulk density

(g/ml)

Moisture

(%)

H2O capacity

(%)

Size ratio up to grade

(%)

Wear ratio

(%)

4A bead4-8 mesh3.0-5.0≥0.70≤1.5
 
≥21.5 ≥98.0
≤0.40
 
bead8-12mesh1.7-2.50≥.70
pallet1/16(inch)1.6≥0.68≥96.0
 
pallet1/8(inch)3.2≥0.68

 

5A Molecular Sieve, is an alkali alumina silicate. It is the calcium form of the type A crystal structure.It has an effective pore opening of 5 angstroms(0.5nm). It will adsorb molecules with a kinetic diameter of less than 5 angstrom and exclude those larger.

 

Properties and Characteristics of Molecular Sieve of 5A
TypeFormBead or Particle size

Diameter

(mm)

Bulk density

(g/ml)

Moisture

(%)

H2O capacity

(%)

Size ratio up to grade

(%)

Wear ratio

(%)

5A bead4-8 mesh3.0-5.0≥0.66≤1.5
 
≥21.5 ≥98.0
≤0.20
 
bead8-12mesh1.7-2.5
pallet1/16(inch)1.6≥0.64 ≥96.0
 
pallet1/8(inch)3.2

 

13X Molecular Sieve, is the sodium form of the type X crystal and has a much larger pore opening than the type A crystals. It will adsorb molecules with a kinetic diameter of less than 10 Angstrom(1.0nm) and exclude those larger.

 

Properties and Characteristics of Molecular Sieve of 13X
TypeFormBead or Particla size

Diameter

(mm)

Bulk density

(g/ml)

Moisture

(%)

H2O capacity

(%)

Size ratio up to grade

Water Ratio

(%)

13Xbead4-8 mesh3.0-5.0≥0.66 ≤1.5≥25≥98.0≤0.20
bead8-12mesh1.7-2.5
pallet1/16(inch)1.6≥0.64 ≥96.0
pallet1/8(inch)3.2

 

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